0000950134-06-004061 Sample Contracts

GUARANTEE
Guarantee • March 1st, 2006 • Valero Energy Corp/Tx • Petroleum refining • New York

GUARANTEE dated as of September 2, 2005 of The Premcor Refining Group Inc., a Delaware corporation (“Premcor Refining”), for the benefit of J.P. Morgan Trust Company, National Association (“JPMorgan”) and The Bank of New York Trust Company, N.A., as successor trustee to The Bank of New York (“BONY”) (collectively, the “Trustees”), and holders (“Holders”) from time to time of the Notes (as defined herein) of Valero Energy Corporation, a Delaware corporation and the indirect parent of Premcor Refining (“Valero”).

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The Premcor Refining Group Inc. and Valero Energy Corporation, as Guarantor, To Deutsche Bank Trust Company Americas Trustee FOURTH SUPPLEMENTAL INDENTURE Dated as of September 1, 2005 6⅛% Senior Notes due 2011 63/4% Senior Notes due 2014
Fourth Supplemental Indenture • March 1st, 2006 • Valero Energy Corp/Tx • Petroleum refining • New York

FOURTH SUPPLEMENTAL INDENTURE, dated as of September 1, 2005 (this “Fourth Supplemental Indenture”) and effective as of the effective time (the “Effective Time”) of the Merger (as defined below), among The Premcor Refining Group Inc., a corporation duly organized and existing under the laws of the State of Delaware (the “Company”), having its principal executive office at 1700 East Putnam Avenue, Suite 400, Old Greenwich, CT 06870, Valero Energy Corporation, a corporation duly organized and existing under the laws of the State of Delaware (“Valero”), and Deutsche Bank Trust Company Americas, a New York banking corporation, as Trustee (the “Trustee”).

GUARANTEE
Guarantee • March 1st, 2006 • Valero Energy Corp/Tx • Petroleum refining • New York

GUARANTEE dated as of September 2, 2005 of Valero Energy Corporation, a Delaware corporation (“Valero”), for the benefit of Deutsche Bank Trust Company Americas (“Deutsche Bank”) and HSBC Bank USA, National Association (successor by merger to HSBC Bank USA) (“HSBC” and, together with Deutsche Bank, the “Trustees”), and holders (“Holders”) from time to time of the Notes (as defined herein) of The Premcor Refining Group Inc., a Delaware corporation and an indirect, wholly owned subsidiary of Valero (the “Company”), and Port Arthur Finance Corp., a Delaware corporation and an indirect, wholly owned subsidiary of the Company (“PAFC”).

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