0001193125-06-227669 Sample Contracts

COMMON STOCK PURCHASE WARRANT To Purchase 1,000,000 Shares of $0.0001 par value Common Stock of Star Scientific, Inc.
Common Stock Purchase Warrant • November 8th, 2006 • Star Scientific Inc • Cigarettes

THIS COMMON STOCK PURCHASE WARRANT (the “Warrant”) CERTIFIES that, for value received, Delaware Charter Guarantee and Trust Company, FBO Joseph L. Schwarz, IRA (the “Holder”), is entitled, upon the terms and subject to the limitations on exercise and the conditions hereinafter set forth, at any time on or after February 25, 2005 (the “Initial Exercise Date”) and on or prior to the close of business on July 15, 2006 (the “Termination Date”) but not thereafter (the “Exercise Period”), to subscribe for and purchase from Star Scientific, Inc., a corporation incorporated in Delaware (the “Company”), up to 1,000,000 shares (the “Warrant Shares”) of Common Stock, par value $0.0001 per share, of the Company (the “Common Stock”). The purchase price of one share of Common Stock (the “Exercise Price”) under this Warrant shall be $4.15, subject to adjustment hereunder. The Exercise Price and the number of Warrant Shares for which the Warrant is exercisable shall be subject to adjustment as provide

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AMENDMENT NO. 1 TO THE SECURITIES PURCHASE AND REGISTRATION RIGHTS AGREEMENT
Securities Purchase and Registration Rights Agreement • November 8th, 2006 • Star Scientific Inc • Cigarettes • New York

This Amendment No. 1 to the Securities Purchase and Registration Rights Agreement (this “Amendment”) is entered into effective as of June 15, 2006 (the “Effective Date”) by and between Star Scientific, Inc., a Delaware corporation (the “Company”) and Elliott Associates, L.P. (the “Investor” and together with the Company, the “Parties”).

AMENDMENT NO. 3 TO THE SECURITIES PURCHASE AND REGISTRATION RIGHTS AGREEMENT
Securities Purchase and Registration Rights Agreement • November 8th, 2006 • Star Scientific Inc • Cigarettes • New York

This Amendment No. 3 to the Securities Purchase and Registration Rights Agreement (this “Amendment”) is entered into effective as of June 15, 2006 (the “Effective Date”) by and between Star Scientific, Inc., a Delaware corporation (the “Company”) and Delaware Charter Guarantee and Trust Company, FBO Joseph C. Schwarz, IRA (the “Investor” and together with the Company, the “Parties”).

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