Anisotropic dipolar hyperfine Sample Clauses

Anisotropic dipolar hyperfine. For the 14N system, the hyperfine part of the Hamiltonian (equation 2.2.3.1) is composed of two terms: the isotropic and anisotropic hyperfine. The isotropic hyperfine,   hAiso Sz  I z , is a result of the transfer of the electron’s spin orbital with the spin orbital of the nucleus. The magnetic field does not affect the splitting caused by the interaction of the spin with surrounding nuclei, so the molecular orientation of the system is not affected. The second term is the anisotropic dipolar hyperfine,  S  Adip  I , which expresses the dependence of the hyperfine splitting on the orientation. The classical expression for the dipolar interaction energy between a fixed electron and nucleus separated by a distance r is: Edip  e   N
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