Exact Cancellation: Nuclear quadrupole interactions Sample Clauses

Exact Cancellation: Nuclear quadrupole interactions. ESEEM spectroscopy is a technique well suited for studying the remote nitrogens of the copper ligating histidines or imidazoles (i.e. those imidazole nitrogens that are not directly coordinated to copper). The quadrupole moment in 14N gives rise to the modulation patterns observed in ESEEM spectra. The corresponding spin Hamiltonian for 14N is: H N  g N  N  I  hS  AN  I  I 'Q  I '
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