Terpenoids Sample Clauses

Terpenoids. The terpenoids or isoprenoids are another of the major plant metabolite groups. The isoprenoid pathway generates both primary and secondary metabolites (XxXxxxxx and Xxxxxxx, 1995). In primary metabolism the isoprenoids have functions as phytohormones (gibberellic acid, abscisic acid and cytokinins) and membrane stabilizers (sterols), and they can be involved in respiration (ubiquinones) and photosynthesis (chlorophylls and plastoquinones); while in secondary metabolism they participate in the communication and plant defense mechanisms (phytoalexins). In cannabis 120 terpenes have been identified (ElSohly and Xxxxx, 2005): 61 monoterpenes, 52 sesquiterpenoids, 2 triterpenes, one diterpene and 4 terpenoid derivatives (Figure 10). The terpenes are responsible for the flavor of the different varieties of cannabis and determine the preference of the cannabis users. The sesquiterpene caryophyllene oxide is the primary volatile detected by narcotic dogs (Xxxxx and Xxxxx, 1973). It has been observed that terpene yield and floral aroma vary with the degree of maturity of female flowers (Mediavilla and Xxxxxxxxxx, 1997) and it has been suggested that terpene composition of the essential oil could be useful for the chemotaxonomic analysis of cannabis plants (Xxxxxx, 2004). Pharmacological effects have been detected for some cannabis terpenes and they may synergize the effects of the cannabinoids (Xxxxxxxx et al., 1975; XxXxxxxxxx and Xxxxxxxxxx, 2002). Terpenes have been detected and isolated from the essential oil from flowers (Xxxx and XxXxxxx, 1996), roots (Xxxxxxx et al., 1971) and leaves (Xxxxxx et al., 1976; Xxxxxxxx et al., 1978); however, the glandular hairs are the main site of localization (Malingre et al., 1975). CHO SESQUITERPENES Ipsdienol Limonene Safranal α-Phellandrene Geraniol O Caryophyllene oxide Humulene α-Curcumene α-Selinene α-Guaiene Farnesol DITERPENES OH Phytol TRITERPENES Epifriedelanol O H O H OH OH H OH OH MEGASTIGMANES O O Dihydrovomifoliol β-Ionone APOCAROTENE Dihydroactinidiolide O Figure 10. Some examples of isolated terpenoids from C. sativa.
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