Task-14 Sample Clauses

Task-14. Photoelectrolytic Production of Hydrogen (Jul/99 – Mar/04) Photoelectrolysis of water is the process whereby light is used to directly split water into hydrogen and oxygen. This can be achieved by placing a photoelectrochemical (PEC), semiconducting material or device similar to a photovoltaic (PV) cell into an electrolyte such as water. Upon irradiation with sunlight, electron-hole pairs are being generated at the catalytic PEC–electrolyte interface, driving chemical hydrogen and oxygen evolution reactions. Herewith, the optical solar energy is directly converted into chemical energy rather than into electrical energy as with solid-state or electrochemical PV cells. Such PEC water splitting systems eliminate the need for two separate systems regarding power generation and electrolysis, and hence offer great potential for cost reduction of electrolytically produced hydrogen compared with conventional two-step technologies. RD&D programs on photoelectrolysis of water have been in place in IEA member countries such as the United States, Japan, Sweden, and Switzerland for many years with encouraging early scientific and laboratory trial device results. However, significant fundamental as well as applied science and engineering efforts are required for the development of practical demonstration systems through a collaborative RD&D program managed by the HIA. Addressing materials and systems studies, the main target areas for RD&D during this 5-year period included: • Practical system efficiency; • Device lifetime and costs; • Semiconductor materials, structures and preparations; • Light sensitisation using photosensitive dyes; • Integrated PV/electrolysis systems; and • Novel single- and dual-bed reactor arrangements.
Sample 1
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